172269-75-9Relevant academic research and scientific papers
Selective Synthesis of Monoaryl Substituted Porphyrins
Robinsohn, Adriana E.,Buldain, Graciela Y.
, p. 1567 - 1572 (2007/10/03)
A synthetic route to meso-monoarylporphyrins using a MacDonald-type 2+2 condensation is described.In this method a bisformyl substituted dipyrrylmethane is treated with a biscarboxydipyrrylmethane.The 5-aryldipyrrylmethanes 15, 25 and 27 were obtained by condensation of the corresponding pyrroles 18, 28 and 29 respectively with benzaldehyde in presence of p-toluenesulfonic acid.
