17227-17-7Relevant academic research and scientific papers
Mild and efficient protection of diol and carbonyls as cyclic acetals catalysed by iron (III) chloride
Karamé, Iyad,Alamé, Mohamad,Kanj, Ali,Baydoun, Ghinwa Nemra,Hazimeh, Hassan,El Masri, Mirvat,Christ, Lorraine
experimental part, p. 525 - 529 (2012/05/19)
A friendly method for the protection of diols and carbonyls catalysed by hexahydrated iron (III) chloride has been developed. This method, which consists of the transformation of diols and carbonyls to cyclic acetals, functions in mild conditions and it is efficient for a wide range of diols.
Selective radical-chain epimerisation at C-H centres α to oxygen under conditions of polarity-reversal catalysis
Dang, Hai-Shan,Roberts, Brian P.
, p. 4271 - 4274 (2007/10/03)
Polarity-reversal catalysis by tri-tert-butoxysilanethiol has been applied to promote radical-chain epimerisation selectively at carbon centres of the type R1R2C*(H)OR.
