17235-14-2

Basic information

• Product Name: 2-[(Z)-3-Hydroxy-3-methyl-1-butenyl]phenol
• Synonyms: 2-[(Z)-3-Hydroxy-3-methyl-1-butenyl]phenol
• CAS NO: 17235-14-2
• Molecular Formula: C₁₁H₁₄O₂
• Molecular Weight: 0
• Mol File: 17235-14-2.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-[(Z)-3-Hydroxy-3-methyl-1-butenyl]phenol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[(Z)-3-Hydroxy-3-methyl-1-butenyl]phenol(17235-14-2)
• EPA Substance Registry System: 2-[(Z)-3-Hydroxy-3-methyl-1-butenyl]phenol(17235-14-2)

Safety Data

• Hazardous Substances Data: 17235-14-2(Hazardous Substances Data)

Upstream product

• 6093-67-0 5-hydroxycoumarin 
• 917-54-4 methyllithium 
• 254-04-6 2H-chromene 
• 939-18-4 3-bromo-2H-chromen-2-one 
• 917-64-6 methyl magnesium iodide 
• 91-64-5 coumarin 
• 271-89-6 1-benzofurane 
• 67-64-1 acetone 

Downstream Products

• 2513-25-9 2,2-dimethyl-2H-chromene 
• 36852-15-0 4-(2-Hydroxyphenyl)-3-methyl-1,3-butadien 
• 398454-32-5 3-(2-hydroxyphenyl)-5,5-dimethyltetrahydrofuran-2-ol 

Relevant articles and documents

2H-chromenes generated by an iron(III) complex-catalyzed allylic cyclization

A straightforward method based on an iron(III) complex-catalyzed cyclization of 2-(1-hydroxyallyl)phenols is reported to access a large variety of 2H-chromenes. This method was applied to the total synthesis of a natural product, tephrowatsin B.

Photochemical Reactions of o-Alkenylphenols and 1-Alkenyl-2-naphthol with Alkylamines: Amination via Photoinduced Proton Transfer

Irradiation of o-alkenylphenols 1a-c and 2a-e in the presence of alkylamines gave o-(1-alkylaminoalkyl)phenols 4a-n and 5a-e in relatively good yields.Deprotonation of these o-alkenylphenols by the amines occurs in the excited singlet state to give the excited singlet state of the phenolate anion 7 and the ammonium ion.The proton transfer from the ammonium ion to the alkenyl group of 7 generates the zwitterion 8 that allows the nucleophilic addition of the amine at the benzylic cation centre.Similar photoamination of 1-(2-methylpropenyl)-2-naphthol 3 with alkylamines occured to give 1-(1-alkylamino-2-methylpropyl)-2-naphthols 6a-b.