172364-77-1

Upstream product

• 169137-91-1 [(Z)-2-((R)-Toluene-4-sulfinyl)-1-trifluoromethyl-vinyl]-carbamic acid benzyl ester 
• 501-53-1 benzyl chloroformate 
• 81357-08-6 benzyl (triphenyl-λ⁵-phosphanilidene)carbamate 
• 364049-52-5 (-)-(2S,S_S)-2-(N-benzyloxycarbonyl)amino-3,3,3-trifluoropropyl-1-(1-naphtyl)sulfoxide 
• 169138-02-7 [(S)-2,2,2-Trifluoro-1-((R)-toluene-4-sulfinylmethyl)-ethyl]-carbamic acid benzyl ester 
• 177268-11-0 C₁₈H₁₈F₃NO₃S 

Downstream Products

• 177469-13-5 (-)-(2R)-N-benzyloxycarbonyl-3,3,3-trifluoroalanine 

Relevant academic research and scientific papers

Enantioselective synthesis of fluorinated α-amino acids and derivatives in combination with ring-closing metathesis: Intramolecular π-stacking interactions as a source of stereocontrol

(Equation presented) Hydride reduction of C=N bonds stereocontrolled by intramolecular π-stacking interactions of 1-naphthylsulfinyl and N-aryl groups, nonoxidative Pummerer rearrangement, and ring-closing metathesis are efficiently combined in a highly s

New versatile fluorinated chiral building blocks: Synthesis and reactivity of optically pure α-(fluoroalkyl)-β-sulfinylenamines

Efficient synthesis of optically pure α-(fluoroalkyl)-β-sulfinyl enamines has been achieved by aza-Wittig reaction of triphenyliminophosphoranes with the corresponding α-fluorinated-α'-sulfinyl ketones. The title compounds 3,4 showed an overwhelming prefe

Unusual Non-Oxidative Pummerer Rearrangement of γ-Trifluoro-β-aminosulfoxides

Trifluoroacetic anhydride promoted Pummerer rearrangement of γ-trifluoro-β-aminosulfoxides 1 follows an unusual pathway, in which a migration of the p-tolylthio group to the nitrogen atom provides the corresponding α-sulfenamidotrifluoroacetates 5.The usu