172472-91-2Relevant academic research and scientific papers
Stereocontrolled photooxygenations - A valuable synthetic tool
Adam, Waldemar,Saha-Moeller, Chantu R.,Schambony, Simon B.,Schmid, Katharina S.,Wirth, Thomas
, p. 476 - 483 (1999)
The stereochemical course of the singlet-oxygen ene reaction with acyclic olefins may be controlled if in the substrate conformational fixation (1,3-allylic strain) an allylic substituent for interaction with the attacking oxygen enophile aligns. Various
Diastereoselective synthesis of merucathin: The singlet oxygen ene reaction (Schenck reaction) as a key step towards an E-configured β-amino allylic alcohol
Adam,Brunker
, p. 1066 - 1068 (2007/10/02)
An enantio- and diastereoselective synthesis of the naturally occurring merucathin is reported. The singlet oxygen ene reaction of the bis-Boc-protected allylic amine 3, which was prepared from L-alanine, was employed as key step for this regio- and diast
