172822-91-2Relevant articles and documents
Regio- and stereoselectivity control in palladium-catalyzed allylic alkylation of 1-cycloalkenylmethyl acetates
Jacquet, Olivier,Legros, Jean-Yves,Coliboeuf, Matthieu,Fiaud, Jean-Claude
, p. 6530 - 6536 (2008/09/21)
Enantiomerically pure allylic acetates 1a and 1b were obtained by lipase-catalyzed acylation through kinetic resolution processes of the racemates. Palladium-catalyzed alkylation of 1a with dimethyl malonate was both regio- and stereoselective, showing th