172847-89-1

Basic information

• Product Name: 2',4',6'-Trimethoxyphenyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside
• Synonyms: 2',4',6'-Trimethoxyphenyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside
• CAS NO: 172847-89-1
• Molecular Weight: 722.899
• Mol File: 172847-89-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2',4',6'-Trimethoxyphenyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 2',4',6'-Trimethoxyphenyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside(172847-89-1)
• EPA Substance Registry System: 2',4',6'-Trimethoxyphenyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside(172847-89-1)

Safety Data

• Hazardous Substances Data: 172847-89-1(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 172847-88-0 2',4',6'-Trimethoxyphenyl 1-thio-β-D-glucopyranoside 
• 13265-84-4 D-glucal 
• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 172847-87-9 2',4',6'-Trimethoxyphenyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside 
• 77189-99-2 2,4,6-trimethoxybenzenethiol 
• 621-23-8 1,2,3-trimethoxybenzene 

Downstream Products

• 165680-85-3 methyl 2,3,4-tri-O-benzoyl-6-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-α-D-glucopyranoside 
• 130050-83-8 methyl 2,3,4-tri-O-benzoyl-6-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-α-D-glucopyranoside 
• 19488-61-0 methyl 2,3,4,6-tetra-O-benzyl α-D-glucopyranoside 
• 3879-79-6 methyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside 

Relevant articles and documents

α-Selective Glycosylation with β-Glycosyl Sulfonium Ions Prepared via Intramolecular Alkylation

Stereoselective glycosylation remains the main challenge in the chemical synthesis of oligosaccharides. Herein we report a simple method to convert thioglycosides into β-sulfonium ions via an intramolecular alkylation reaction, leading to highly α-selective glycosylations for a variety of glycosyl acceptors. The influence of the thioglycoside substituent and the protecting group pattern on the glycosyl donor was investigated and showed a clear correlation with the observed stereoselectivity.