172987-48-3Relevant academic research and scientific papers
Syntheses and X-ray crystal structures of five- and six-coordinated iron(I) and iron(II) complexes with the same (η5-C5Me5)Fe(dppe) framework
Hamon, Paul,Toupet, Lo?c,Hamon, Jean-René,Lapinte, Claude
, p. 10 - 12 (1996)
The one electron reduction of Cp*Fe(dppe)-(OSO2CF3) (2) with cobaltocene gave the d7 iron(I) Cp*Fe(dppe) (3, 90%) as thermally stable orange crystals, whereas the one-electron oxidation of 3 with ferrocenium hexafluorophos
Preparation and Characterization of the Triflate Complex [Cp*(dppe)FeOSO2CF3]: A Convenient Access to Labile Five- and Six-Coordinate Iron(I) and Iron(II) Complexes
Hamon, Paul,Toupet, Loic,Roisnel, Thierry,Hamon, Jean-René,Lapinte, Claude
, p. 84 - 93 (2019/12/12)
Treatment of the iron hydride [Cp*(dppe)FeH] (1) with methyl triflate (CH3OSO2CF3) yielded the iron triflate adduct [Cp*(dppe)FeOSO2CF3] (4, 85 %). In the solid state, the triflate is coordinated at t
