172998-55-9

Upstream product

• 6833-21-2 2-methoxy-N-phenylbenzamide 
• 100-39-0 benzyl bromide 
• 579-75-9 2-Methoxybenzoic acid 
• 21615-34-9 2-Methoxybenzoyl chloride 
• 1007693-86-8 N-benzyl-2-hydroxy-N-phenylbenzamide 
• 74-88-4 methyl iodide 
• 19672-91-4 N-benzyl-N-phenylbenzamide 

Downstream Products

• 1616495-17-0 7-benzyldibenzo[d,f][1,3]oxazepin-6(7H)-one 
• 1007693-86-8 N-benzyl-2-hydroxy-N-phenylbenzamide 
• 55589-69-0 2′-amino-[1,1′-biphenyl]-2-ol 

Relevant academic research and scientific papers

A diversity-oriented synthesis of bioactive benzanilides via a regioselective C(sp2)-H hydroxylation strategy

A diversity-oriented synthesis of bioactive benzanilides via C(sp2)-H hydroxylation has been studied. Different regioselectivity was observed with Ru(ii) and Pd(ii) catalysts. The reaction demonstrates excellent regioselectivity, good tolerance

Intramolecular metal-free oxidative aryl-aryl coupling: An unusual hypervalent-iodine-mediated rearrangement of 2-substituted n-phenylbenzamides

Hypervalent-iodine-mediated oxidative coupling of the two aryl groups in either 2-acylamino-N-phenyl-benzamides or 2-hydroxy-N-phenylbenzamides, with concomitant insertion of the ortho-substituted N or O atom into the tether, has been described for the first time. This unusual metal-free rearrangement reaction involves an oxidative C(sp2)?C(sp2) aryl-aryl bond formation, cleavage of a C(sp2)?C(O) bond, and a lactamization/lactonization. Furthermore, unsymmetrical diaryl compounds can be easily obtained by removing the tether within the cyclized product.