17304-82-4Relevant academic research and scientific papers
Ionic liquid as reagent. A green procedure for the regioselective conversion of epoxides to vicinal-halohydrins using [AcMIm]X under catalyst- and solvent-free conditions
Ranu, Brindaban C.,Banerjee, Subhash
, p. 4517 - 4519 (2007/10/03)
A variety of structurally diverse epoxides undergo facile cleavages by ionic liquid, [AcMIm]X without any catalyst and solvent to produce the corresponding vicinal halohydrins in high yields. The cleavages are considerably fast and highly regioselective.
Oxidation of α,β-enones and alkenes with oxone and sodium halides: A convenient laboratory preparation of chlorine and bromine
Dieter, R. Karl,Nice, Lois E.,Velu, Sadanandan E.
, p. 2377 - 2380 (2007/10/03)
Mixtures of oxone and sodium chloride or sodium bromide afford solutions of chlorine or bromine, respectively. These solutions effectively add chlorine and bromine to α,β-enones and alkenes. The method affords improved yields of 3-alkyl-2-halo-2-cycloalkenones which are sometimes difficult to prepare.
FUNTIONALIZATION OF ISOPHORONE INVOLVING POLYCHLORINATION. PART II: Chlorination of Isophorone in the 2- and 6-position involving addition of chlorine to the double bond. Enol allyl rearrangements and base-induced substitution of the 6-chloro atom.
Buyck, L. De,Bostoen, R.,Lecluse, M.,Pooter, H. De,Schamp, N.
, p. 663 - 674 (2007/10/02)
Using trans-2,3-dichloro-3,5,5-trimethylcyclohexanone (2) as an intermediate, isophorone (1) was converted into the 2-chloro derivative 6 (85-93percent), the 2,6-dichloro derivative 5 (65-75percent) and the 2,6,6-trichloro derivative 10 (60-70percent) (is
HYPOCHLOROUS ACID. REACTION WITH CONJUGATED KETONES A SYNTHESIS OF α-CHLORO-β,γ-UNSATURATED KETONES
Hegde, Shridhar G.,Wolinsky, Joseph
, p. 5019 - 5022 (2007/10/02)
The two-phase reaction of HOCl with more highly substituted conjugated ketones which can exist in an s-cis conformation yield α-chloro-β,γ-unsaturated ketones in good yield.
