17304-82-4

Basic information

• Product Name: 2-CHLORO-3,5,5-TRIMETHYL-CYCLOHEX-2-ENONE
• Synonyms: 2-CHLORO-3,5,5-TRIMETHYL-CYCLOHEX-2-ENONE
• CAS NO: 17304-82-4
• Molecular Formula: C₉H₁₃ClO
• Molecular Weight: 172.65192
• Mol File: 17304-82-4.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-CHLORO-3,5,5-TRIMETHYL-CYCLOHEX-2-ENONE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-CHLORO-3,5,5-TRIMETHYL-CYCLOHEX-2-ENONE(17304-82-4)
• EPA Substance Registry System: 2-CHLORO-3,5,5-TRIMETHYL-CYCLOHEX-2-ENONE(17304-82-4)

Safety Data

• Hazardous Substances Data: 17304-82-4(Hazardous Substances Data)

Upstream product

• 10276-21-8 isophorone oxide 
• 78-59-1 3,5,5-Trimethylcyclohex-2-en-1-one 

Downstream Products

• 113542-70-4 cis-2,2,3,6-tetrachloro-3,5,5-trimethylcyclohexanone 
• 113542-70-4 trans-2,2,3,6-tetrachloro-3,5,5-trimethylcyclohexanone 
• 113542-76-0 4-acetoxy-2-chloroisophorone 
• 113542-67-9 Acetic acid 3-chloro-4,6,6-trimethyl-2-oxo-cyclohex-3-enyl ester 
• 113542-78-2 2-Chloro-6-methoxy-3,5,5-trimethyl-cyclohex-2-enone 
• 113542-68-0 2,4-dichloroisophorone 
• 113542-65-7 2,6-dichloroisophorone 
• 113542-66-8 2,2,3-trichloro-3,5,5-trimethylcyclohexanone 

Relevant articles and documents

Ionic liquid as reagent. A green procedure for the regioselective conversion of epoxides to vicinal-halohydrins using [AcMIm]X under catalyst- and solvent-free conditions

A variety of structurally diverse epoxides undergo facile cleavages by ionic liquid, [AcMIm]X without any catalyst and solvent to produce the corresponding vicinal halohydrins in high yields. The cleavages are considerably fast and highly regioselective.

FUNTIONALIZATION OF ISOPHORONE INVOLVING POLYCHLORINATION. PART II: Chlorination of Isophorone in the 2- and 6-position involving addition of chlorine to the double bond. Enol allyl rearrangements and base-induced substitution of the 6-chloro atom.

Using trans-2,3-dichloro-3,5,5-trimethylcyclohexanone (2) as an intermediate, isophorone (1) was converted into the 2-chloro derivative 6 (85-93percent), the 2,6-dichloro derivative 5 (65-75percent) and the 2,6,6-trichloro derivative 10 (60-70percent) (is