113542-66-8

Basic information

• Product Name: Cyclohexanone, 2,2,3-trichloro-3,5,5-trimethyl-
• CAS NO: 113542-66-8
• Molecular Formula: C9H13Cl3O
• Molecular Weight: 243.561
• Mol File: 113542-66-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 2,2,3-trichloro-3,5,5-trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 2,2,3-trichloro-3,5,5-trimethyl-(113542-66-8)
• EPA Substance Registry System: Cyclohexanone, 2,2,3-trichloro-3,5,5-trimethyl-(113542-66-8)

Safety Data

• Hazardous Substances Data: 113542-66-8(Hazardous Substances Data)

Upstream product

• 78-59-1 3,5,5-Trimethylcyclohex-2-en-1-one 
• 17304-82-4 2-chloroisophorone 

Downstream Products

• 113542-76-0 4-acetoxy-2-chloroisophorone 
• 113542-70-4 trans-2,2,3,6-tetrachloro-3,5,5-trimethylcyclohexanone 
• 113542-70-4 cis-2,2,3,6-tetrachloro-3,5,5-trimethylcyclohexanone 
• 113542-65-7 2,6-dichloroisophorone 
• 113542-73-7 2-chloro-3,5,5-trimethyl-2-cyclopentenecarboxylic acid 
• 113542-67-9 Acetic acid 3-chloro-4,6,6-trimethyl-2-oxo-cyclohex-3-enyl ester 
• 38941-96-7 2-chloro-3,4,5-trimethylphenol 
• 113542-68-0 2,4-dichloroisophorone 
• 113542-74-8 2-Chloro-3,5,5-trimethyl-cyclopent-2-enecarboxylic acid methyl ester 
• 113542-78-2 2-Chloro-6-methoxy-3,5,5-trimethyl-cyclohex-2-enone 

Relevant articles and documents

FUNTIONALIZATION OF ISOPHORONE INVOLVING POLYCHLORINATION. PART II: Chlorination of Isophorone in the 2- and 6-position involving addition of chlorine to the double bond. Enol allyl rearrangements and base-induced substitution of the 6-chloro atom.

Using trans-2,3-dichloro-3,5,5-trimethylcyclohexanone (2) as an intermediate, isophorone (1) was converted into the 2-chloro derivative 6 (85-93percent), the 2,6-dichloro derivative 5 (65-75percent) and the 2,6,6-trichloro derivative 10 (60-70percent) (is