173044-30-9

Basic information

• Product Name: tert-Butyl-[(2E,5E,9E)-12-(3,3-dimethyl-oxiranyl)-3,6,10-trimethyl-dodeca-2,5,9-trienyloxy]-diphenyl-silane
• Synonyms: tert-Butyl-[(2E,5E,9E)-12-(3,3-dimethyl-oxiranyl)-3,6,10-trimethyl-dodeca-2,5,9-trienyloxy]-diphenyl-silane
• CAS NO: 173044-30-9
• Molecular Weight: 530.866
• Mol File: 173044-30-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: tert-Butyl-[(2E,5E,9E)-12-(3,3-dimethyl-oxiranyl)-3,6,10-trimethyl-dodeca-2,5,9-trienyloxy]-diphenyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: tert-Butyl-[(2E,5E,9E)-12-(3,3-dimethyl-oxiranyl)-3,6,10-trimethyl-dodeca-2,5,9-trienyloxy]-diphenyl-silane(173044-30-9)
• EPA Substance Registry System: tert-Butyl-[(2E,5E,9E)-12-(3,3-dimethyl-oxiranyl)-3,6,10-trimethyl-dodeca-2,5,9-trienyloxy]-diphenyl-silane(173044-30-9)

Safety Data

• Hazardous Substances Data: 173044-30-9(Hazardous Substances Data)

Upstream product

• 106-28-5 Farnesol 
• 63058-28-6 (E,E)-1-chloro-10,11-epoxy-3,7,11-trimethyl-2,6-dodecadiene 
• 173044-29-6 C₂₀H₂₅LiOSi 
• 173044-28-5 (E)-2-bromo-4-(tert-butyldiphenylsilyloxy)-2-butene 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 4128-17-0 (2E,6E)-farnesyl acetate 
• 5233-99-8 10,11-epoxyfarnesol 

Downstream Products

• 203317-07-1 (3E,7E,11E,14E)-16-(tert-Butyl-diphenyl-silanyloxy)-7,11,14-trimethyl-hexadeca-3,7,11,14-tetraen-2-one 
• 173044-31-0 (4E,8E,11E)-13-(tert-Butyl-diphenyl-silanyloxy)-4,8,11-trimethyl-trideca-4,8,11-trien-1-ol 

Relevant articles and documents

Concise total synthesis of (±)-palominol and (±)-dolabellatrienone via a dianion-accelerated oxy-Cope rearrangement

A short synthesis of (±)-palominol (1) and (±)-dolabellatrienone (2) starting from farnesol is reported. Noteworthy steps include an intramolecular pinacol coupling to form a 15-membered carbocyclic diol and subsequent dianion-accelerated oxy-Cope rearrangement to form the 11,5-trans-fused ring system of the dolabellanes.