203317-07-1

Upstream product

• 1067-71-6 Diethyl (2-oxopropyl)phosphonate 
• 5233-99-8 10,11-epoxyfarnesol 
• 4128-17-0 (2E,6E)-farnesyl acetate 
• 173044-29-6 C₂₀H₂₅LiOSi 
• 173044-30-9 tert-Butyl-[(2E,5E,9E)-12-(3,3-dimethyl-oxiranyl)-3,6,10-trimethyl-dodeca-2,5,9-trienyloxy]-diphenyl-silane 
• 173044-28-5 (E)-2-bromo-4-(tert-butyldiphenylsilyloxy)-2-butene 
• 63058-28-6 (E,E)-1-chloro-10,11-epoxy-3,7,11-trimethyl-2,6-dodecadiene 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Relevant academic research and scientific papers

Concise total synthesis of (±)-palominol and (±)-dolabellatrienone via a dianion-accelerated oxy-Cope rearrangement

A short synthesis of (±)-palominol (1) and (±)-dolabellatrienone (2) starting from farnesol is reported. Noteworthy steps include an intramolecular pinacol coupling to form a 15-membered carbocyclic diol and subsequent dianion-accelerated oxy-Cope rearrangement to form the 11,5-trans-fused ring system of the dolabellanes.