173096-83-8Relevant academic research and scientific papers
Phosphoramidate-mediated conversion of carbonyl ligands into isocyanide ligands: A new approach to chiral isocyanide ligands
Gibson, Susan E.,Ibrahim, Hasim,Pasquier, Corinne,Peplow, Mark A.,Rushton, Julia M.,Steed, Jonathan W.,Sur, Ojit
, p. 269 - 276 (2002)
Metal isocyanides have been used and studied by organometallic chemists for many years and, as a result, they have a rich and interesting chemistry. The nature of metal-free isocyanides and the methods of making isocyanide complexes, however, has resulted
Synthesis of Enantiomerically Enriched Tricarbonyl(vinylketene)iron(0) Complexes
Benyunes, Stephen A.,Gibson, Suzan E.,Ward, Mark F.
, p. 2517 - 2520 (1995)
Addition of tricarbonyl(vinylketene)iron(0) complexes 2a-d to 0.5 equiv. of a phosphoramidate anion derived from (S)-α-methylbenzylamine affords the first enantiomerically enriched samples of 2a-d; the absolute configurations of 2a-d have been established
Phosphoramidate-mediated conversion of metal carbonyls into metal isonitriles
Gibson, Susan E.,Hinkamp, Thomas W.,Peplow, Mark A.,Ward, Mark F.
, p. 1671 - 1672 (2007/10/03)
The reaction of metal carbonyls with readily-available phosphoramidate anions provides a new route to metal isonitriles; in particular, enantiomerically pure isonitrile complexes are easily accessed by this method.
