173206-23-0Relevant articles and documents
Synthesis of a Symmetric Multivalent Molecule containing four Carbohydrate Substituents
Binder, W. H.,Schmid, W.
, p. 923 - 932 (1995)
Starting with allyl- and pent-4-enyl-β-D-glucopyranosides 4-7, different D-Glucose units (8-15) containing alkyl spacers of variable lenght and with different end groups can be prepared.Reaction of four equivalents of the caesium salt derived from propan-4-carboxyl-1-yl-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside 15 with pentaerythrityltetrabromide yields the tetravalent molecule 16. - Keywords: Carbohydrates; Dendrimers; Spacer.
Use of n-pentenyl glycosides as precursors to various spacer functionalities
Buskas, Therese,Soederberg, Eva,Konradsson, Peter,Fraser-Reid, Bert
, p. 958 - 963 (2007/10/03)
Pent-4-enyl β-D-glucopyranoside and its peracetylated and perbenzylated derivatives are shown to be excellent substrates for preparation of a wide variety of spacer functionalities. The spacer derivatives so obtained are promising substrates for preparing agents such as neo-glycoconjugates, micelies, and liquid crystalline phases, which are of interest for studying various biological and physiological phenomena of carbohydrates.