50256-33-2

Upstream product

• 821-09-0 n-Pent-4-enyl alcohol 
• 1219934-69-6 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl ortho-(hex-1-ynyl)benzoate 

Downstream Products

• 1268469-71-1 C₅₃H₅₉NO₁₃ 
• 1268469-70-0 C₅₃H₅₉NO₁₃ 
• 127570-60-9 n-pent-4-yl 2,3,4-O-tribenzyl-6-O-(tert-butyldiphenylsilyl)-β-D-glucopyranoside 
• 1268469-66-4 n-pent-4-enyl 2,3,4-O-tribenzyl-6-O-chloroacetyl-β-D-glucopyranoside 
• 1268469-69-7 C₃₃H₃₇ClO₈ 
• 1268469-68-6 3-carboxypropyl 2,3,4-O-tribenzyl-6-O-chloroacetyl-β-D-glucopyranoside 
• 155036-27-4 pent-4-enyl 2,3,4-tri-O-benzyl-β-D-glucopyranoside 
• 1453291-51-4 4-hydroxy-5-[4-(p-tolyl)-1,2,3-triazol-1-yl]pentyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside 
• 143535-90-4 (3aR,5R,5aS,8aS,8bR)-5-[(3aS,4R,6S,7R,7aS)-7-(4-Methoxy-benzyloxy)-4-(4-methoxy-benzyloxymethyl)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yloxymethyl]-2,2,7,7-tetramethyl-tetrahydro-bis[1,3]dioxolo[4,5-b;4',5'-d]pyran 
• 143535-91-5 (3aR,5R,5aS,8aS,8bR)-5-[(3aS,4R,6R,7R,7aS)-7-(4-Methoxy-benzyloxy)-4-(4-methoxy-benzyloxymethyl)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yloxymethyl]-2,2,7,7-tetramethyl-tetrahydro-bis[1,3]dioxolo[4,5-b;4',5'-d]pyran 
• 143535-86-8 (3aS,4R,6R,7R,7aS)-7-(4-Methoxy-benzyloxy)-4-(4-methoxy-benzyloxymethyl)-2,2-dimethyl-6-pent-4-enyloxy-tetrahydro-[1,3]dioxolo[4,5-c]pyran 
• 173206-23-0 3-formylpropyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 178249-57-5 pent-4-enyl 4,6-O-benzylidene-2,3-O-ethylene-β-D-glucopyranoside 

Relevant academic research and scientific papers

Identification of 3,6-di-O-acetyl-1,2,4-O-orthoacetyl-α-d- glucopyranose as a direct evidence for the 4-O-acyl group participation in glycosylation

The formation of 3,6-di-O-acetyl-1,2,4-O-orthoacetyl-α-d- glucopyranose was observed in the gold(i)-catalyzed glycosidation of peracetyl glucopyranosyl ortho-hexynylbenzoate; experiments with substrates bearing deuterium labeled 2-O-acetyl or 4-O-acetyl groups indicated that the orthoacetate was derived from the 4-O-acetyl group, which provided a direct evidence for the remote participation of the 4-O-acyl group in glycosylation.