173346-95-7Relevant academic research and scientific papers
An efficient procedure for palladium-catalyzed reduction of aryl/enol triflates
Kotsuki,Datta,Hayakawa,Suenaga
, p. 1348 - 1350 (1995)
An efficient procedure to deoxygenate phenols and enols via trifluoromethanesulfonates is presented. Their reduction with triethylsilane in the presence of a catalytic amount of palladium acetate and bidentate phosphine ligands such as 1,3-bis(diphenylphosphino)propane or 1,1'-bis(diphenylphosphino)ferrocene proceeds efficiently to afford a variety of aromatic, heteroaromatic, and olefinic compounds.
Iodide acceleration in the Pd-catalyzed coupling of aromatic 1,2-ditriflates with alkynes: Synthesis of enediynes
Powell, Noel A.,Rychnovsky, Scott D.
, p. 7901 - 7904 (2007/10/03)
Aryl enediyenes have been synthesized in a one-pot procedure by a Pd-catalyzed coupling of terminal alkynes and ortho-aryl ditriflates. A variety of substrates have been examined.
