Synthesis p. 1348 - 1350 (1995)
Update date:2022-08-05
Topics: Reduction Palladium-Catalyzed
Kotsuki
Datta
Hayakawa
Suenaga
An efficient procedure to deoxygenate phenols and enols via trifluoromethanesulfonates is presented. Their reduction with triethylsilane in the presence of a catalytic amount of palladium acetate and bidentate phosphine ligands such as 1,3-bis(diphenylphosphino)propane or 1,1'-bis(diphenylphosphino)ferrocene proceeds efficiently to afford a variety of aromatic, heteroaromatic, and olefinic compounds.
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Doi:10.1021/om900905c
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(1995)Doi:10.1246/cl.1995.87
(1995)Doi:10.1021/jacs.5b07726
(2015)Doi:10.1016/0960-894X(96)00151-5
(1996)
