An efficient procedure for palladium-catalyzed reduction of aryl/enol triflates

DOI: 10.1055/s-1995-4120

Source and publish data:

Synthesis p. 1348 - 1350 (1995)

Update date:2022-08-05

Topics: Reduction Palladium-Catalyzed

Authors:

Kotsuki Kotsuki

Datta Datta

Hayakawa

Suenaga Suenaga

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Article abstract of DOI:10.1055/s-1995-4120

An efficient procedure to deoxygenate phenols and enols via trifluoromethanesulfonates is presented. Their reduction with triethylsilane in the presence of a catalytic amount of palladium acetate and bidentate phosphine ligands such as 1,3-bis(diphenylphosphino)propane or 1,1'-bis(diphenylphosphino)ferrocene proceeds efficiently to afford a variety of aromatic, heteroaromatic, and olefinic compounds.

Full text of DOI:10.1055/s-1995-4120

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