173392-72-8Relevant academic research and scientific papers
Sodium Sulphide as a Mild and Selective Desilylating Reagent
Schmittberger, T.,Uguen, D.
, p. 7445 - 7448 (2007/10/02)
diphenyl-t-butoxyslyl (i.e.DPTBOS) derivatives of alcohols are selectively cleaved by nonahydrated sodium sulphide in ethanol, the order of reactivity being: primary ca. secondary>>tertiary.The corresponding t-butyldimethylsilyl and diphenyl-t-butylsilyl derivatives remain unaffected in these conditions.
