173395-56-7Relevant academic research and scientific papers
A Ramberg-Backlund approach to exo-glycals
Griffin, Frank K.,Murphy, Paul V.,Paterson, Duncan E.,Taylor, Richard J.K.
, p. 8179 - 8182 (2007/10/03)
A new route to exo-glycals is described which starts from S-glycoside dioxides and utilises Meyers' variant of the Ramberg-Backlund rearrangement. The methodology is successful with glucose, galactose, mannose, xylose, fucose and ribose derivatives, and has been used to prepare di-, tri- and tetra-substituted alkenes.
Activation and synthetic applications of thiostannanes. A new method for synthesis of thio- and selenoglycosides
Sato, Tsuneo,Fujita, Yukihiro,Otera, Junzo,Nozaki, Hitosi
, p. 239 - 242 (2007/10/02)
Exposure of thiostannane to acetyl or methyl glycosides in the presence of a catalytic amount of Bu2Sn(OTf)2 provides thioglycosides in good yields. Selenoglycosidation is achieved in a like manner by use of selenostannane.
