173409-84-2Relevant academic research and scientific papers
Synthesis and Stereochemistry of 8-Methyl-5-nitro-1-octalones
Halasz, J.,Toth, G.,Kadas, I.,Arvai, G.,Miklo, K.,Haessner, R.
, p. 1011 - 1020 (1995)
Base catalyzed Michael addition of 5-nitropentan-2-one ethylene ketal (1) and cyclohex-2-enone (2), subsequent deprotection, and intramolecular aldol condensation yields the 8-methyl-5-nitro-1-octalone isomers (5a,b).The structure, relative configuration,
Phase-Transfer-Catalyst-Mediated Domino Reaction of γ-Nitro Ketones with Chalcones: Approach to Functionalized Six-Membered-Ring Carbocycles
Yu, Lu,Yang, Qingjing,Li, Pengfei
, p. 7499 - 7504 (2014)
Domino reactions between γ-nitro ketones and chalcones for the construction of functionalized six-membered-ring carbocycles using a phase-transfer catalyst have been developed. In the presence of tetrabutylammonium iodide and potassium hydroxide, domino r
Direct and indirect radical denitrations of intermediates in the synthesis of sorgolactone and its nuclear analogs
Miklo, Katalin,Jaszberenyi, Joseph Cs.,Kadas, Istvan,Arvai, Geza,Toke, Laszlo
, p. 3491 - 3494 (2007/10/03)
Denitration of various important intermediates in the synthesis of sorgolactone and its analogs using radical chemistry on nitroketones or on the derived isocyanides is described. The nitro group is needed for the first step of the annellation process, th
