Synthesis and Stereochemistry of 8-Methyl-5-nitro-1-octalones

DOI: 10.1007/BF00811021

Source and publish data:

Monatshefte fur Chemie p. 1011 - 1020 (1995)

Update date:2022-08-16

Topics:

Authors:

Halasz, J.

Toth, G.

Kadas, I.

Arvai, G.

Miklo, K.

Haessner, R.

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Article abstract of DOI:10.1007/BF00811021

Base catalyzed Michael addition of 5-nitropentan-2-one ethylene ketal (1) and cyclohex-2-enone (2), subsequent deprotection, and intramolecular aldol condensation yields the 8-methyl-5-nitro-1-octalone isomers (5a,b).The structure, relative configuration,

Full text of DOI:10.1007/BF00811021

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