173425-80-4

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 34361-60-9 1L-1,2:4,5-di-O-cyclohexylidene-myo-inositol 
• 824-94-2 p-methoxybenzyl chloride 

Downstream Products

• 173425-83-7 C₂₈H₃₂O₈ 
• 173425-90-6 C₃₅H₃₈O₁₀S 
• 173425-91-7 Toluene-4-sulfonic acid (1R,2R,3S,4R,4aR,11bS)-2,3-dihydroxy-4-(4-methoxy-benzyloxy)-2,3,4,4a,6,11b-hexahydro-1H-5,8,10-trioxa-cyclopenta[b]phenanthren-1-yl ester 
• 173425-87-1 (1R,2S,3S,4R,4aR,11bR)-1-Azido-4-(4-methoxy-benzyloxy)-2,3,4,4a,6,11b-hexahydro-1H-5,8,10-trioxa-cyclopenta[b]phenanthrene-2,3-diol 
• 173425-82-6 C₂₈H₃₁BrO₈ 
• 173425-86-0 C₂₂H₂₂O₇ 
• 173425-81-5 C₂₀H₂₆O₆ 

Relevant academic research and scientific papers

An approach to pancratistatin from myo-inositol

A highly advanced intermediate (15) for the synthesis of 7-deoxypancratistatin was prepared in 11 steps from myo-inositol. Introduction of the C(10b)-Ar bond through an intramolecular epoxide opening with an aryl anion is the key step in this approach.