An approach to pancratistatin from myo-inositol

DOI: 10.1016/0040-4039(95)02070-5

Source and publish data:

Tetrahedron Letters p. 13 - 16 (1996)

Update date:2022-09-26

Topics:

Authors:

Gauthier Jr., Donald R.

Bender, Steven L.

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Article abstract of DOI:10.1016/0040-4039(95)02070-5

A highly advanced intermediate (15) for the synthesis of 7-deoxypancratistatin was prepared in 11 steps from myo-inositol. Introduction of the C(10b)-Ar bond through an intramolecular epoxide opening with an aryl anion is the key step in this approach.

Full text of DOI:10.1016/0040-4039(95)02070-5

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