Tetrahedron Letters p. 13 - 16 (1996)
Update date:2022-09-26
Topics:
Gauthier Jr., Donald R.
Bender, Steven L.
A highly advanced intermediate (15) for the synthesis of 7-deoxypancratistatin was prepared in 11 steps from myo-inositol. Introduction of the C(10b)-Ar bond through an intramolecular epoxide opening with an aryl anion is the key step in this approach.
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