173537-09-2

Upstream product

• 173537-08-1 (3Z,10E,12E)-3-(methoxymethoxy)methyl-1-acetoxy-7,7-bis(methoxycarbonyl)-14-tert-butyldiphenylsiloxytetradeca-3,10,12-triene 
• 173536-84-0 (E,E)-8-tert-butyldiphenylsiloxy-1,1-bis(methoxycarbonyl)-4,6-octadiene 
• 149311-09-1 (2E,4E)-7-(Tetrahydro-pyran-2-yloxy)-hepta-2,4-dien-1-ol 
• 149310-67-8 ethyl (E)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-2-enoate 
• 92844-99-0 (2E)-5-<(2-tetrahydropyranyl)oxy>pent-2-en-1-ol 
• 172472-92-3 (Z)-3-(3'-tert-butyldimethylsiloxy)propylideneoxolan-2-one 
• 173536-91-9 2-[3-(tert-Butyl-dimethyl-silanyloxy)-prop-(Z)-ylidene]-butane-1,4-diol 
• 173536-94-2 (Z)-3-hydroxymethyl-1-acetoxy-6-tert-butyldimethylsiloxy-3-hexene 
• 173536-93-1 Acetic acid (Z)-6-(tert-butyl-dimethyl-silanyloxy)-3-formyl-hex-3-enyl ester 
• 173536-95-3 (Z)-3-(methoxymethoxy)methyl-1-acetoxy-6-tert-butyldimethylsiloxy-3-hexene 
• 144344-25-2 2,2-Dimethyl-propionic acid (Z)-6-methanesulfonyloxy-3-methoxymethoxymethyl-hex-3-enyl ester 
• 173536-83-9 Methanesulfonic acid (3E,5E)-7-(tert-butyl-diphenyl-silanyloxy)-hepta-3,5-dienyl ester 
• 173536-82-8 tert-Butyl-diphenyl-[(2E,4E)-7-(tetrahydro-pyran-2-yloxy)-hepta-2,4-dienyloxy]-silane 
• 172473-07-3 (E-E)-1-tert-butyldiphenylsiloxy-2,4-heptadien-7-ol 

Downstream Products

• 173537-11-6 (4Z,11E,13E)-4-(methoxymethoxy)methyl-1,1,8,8-tetrakis(methoxycarbonyl)-15-tert-butyldiphenylsiloxypentadeca-4,11,13-triene 
• 173537-10-5 2-[(3E,5E)-7-(tert-Butyl-diphenyl-silanyloxy)-hepta-3,5-dienyl]-2-((Z)-6-methanesulfonyloxy-4-methoxymethoxymethyl-hex-3-enyl)-malonic acid dimethyl ester 

Relevant academic research and scientific papers

Studies on the transannular Diels-Alder reaction of 15-membered macrocyclic trienes containing a trans-trans diene. Part I: Synthesis and isomerization of various model cyclopentadecatrienes

The transannular Diels-Alder reaction of 15-membered macrocyclic trienes with a trans-trans-cis (TTC) olefin geometry can lead to A.B.C. tricyclic products of trans-syn-trans (TST) and cis-syn-cis (CSC) stereochemistry whereas the TTT isomers can p

Transannular Diels-Alder Reaction of Trans-Trans-Cis 15-Membered Macrocyclic Trienes. Evidence for Asynchronous Transition State.

The transannular Diels-Alder reaction of trans-trans-cis 15-membered macrocyclic trienes 1, 6, 7 leading to A.B.C. tricyclic compounds is described.