173595-37-4

Upstream product

• 124-63-0 methanesulfonyl chloride 
• 123956-70-7 2,3,6-tri-O-benzoyl-N-(2,2-diethoxycarbonylvinyl)-β-D-glucopyranosylamine 

Downstream Products

• 173595-38-5 1,4-anhydro-2,3,6-tri-O-benzoyl-N-(2,2-diethoxycarbonylvinyl)-β-D-galactopyranosylamine 
• 198640-99-2 (2S,3S,4R,5S)-3,4-dibenzoyloxy-2((1'S)-2'-benzoyloxy-1'-hydroxyethyl)-1-(2,2-diethoxycarbonylvinyl)-5-methoxypyrrolidine 

Relevant academic research and scientific papers

Stereoselective syntheses of 4-amino-aldoses, and chiral pyrrolidine derivatives from glycosylenamines

The stereocontrolled synthesis of N-protected 4-amino-4-deoxy-D-galacto and -L-arabino-pyranoses starting from glycosylenamines via aza- anhydropyranoses is described. The steroselective transformation of the intermediate aza-anhydropyranoses into chiral pyrrolidines is also reported.