1736-12-5

Upstream product

• 85290-62-6 2-phenylamino-1,1,3,3,3-pentafluoropropene 
• 299929-60-5 2,4,6-tris[(1,1,1,3,3,3-hexafluoropropan-2-yl)oxy]-1,3,5-triazine 
• 62-53-3 aniline 
• 103-71-9 phenyl isocyanate 
• 334866-55-6 [1-({2-[1-(tert-butyl-dimethyl-silanyloxy)-2,2,2-trifluoro-1-trifluoromethyl-ethyl]-phenylselanyl}-phenyl-methyl)-2,2,2-trifluoro-1-trifluoromethyl-ethyl]-phenyl-amine 
• 334866-56-7 1,1,1,3,3,3-hexafluoro-2-[2-(3,3,3-trifluoro-1-phenyl-2-phenylamino-2-trifluoromethyl-propylselanyl)-phenyl]-propan-2-ol 
• 910110-24-6 2-[1-t-butyldimethylsiloxy-2,2,2-trifluoro-1-(trifluoromethyl)ethyl]phenyl 3,3,3-trifluoro-1-phenyl-2-phenylamino-2-(trifluoromethyl)propyl sulfide 
• 910110-25-7 2-phenylamino-1-phenyl-3,3,3-trifluoro-2-(trifluoromethyl)propyl 2-[2,2,2-trifluoro-1-hydroxy-1-(trifluoromethyl)ethyl]phenyl sulfide 
• 910110-29-1 trans-2',4'-diphenyl-3,3,3',3'-tetrakis(trifluoromethyl)-3H-spiro[[2,1]benzoxathiole-1λ⁶,1'-[1,2]thiazetidine] 1-oxide 
• 105504-55-0 bis(1-trifluoromethyl-2,2,2-trifluoroethoxy)triphenylphosphorane 
• 917-64-6 methyl magnesium iodide 
• 2002-95-1 N-(hexafluoroisopropylidene)aniline 

Downstream Products

• 85290-62-6 2-phenylamino-1,1,3,3,3-pentafluoropropene 

Relevant academic research and scientific papers

Synthesis, crystal structure, and thermolysis of the first tetracoordinate 1λ4,2-selenazetidines: Aziridine formation reaction from a four-membered heterocycle bearing highly coordinate selenium

Equation presented The first tetracoordinate 1λ4,2-selenazetidines were synthesized by taking advantage of the Martin ligand and characterized by X-ray crystallographic analysis. The selenazetidines gave the corresponding aziridine and the cyclic selenenate on their thermolysis, which indicates the possibiliy that a highly coordinate 1,2-heterachalcogenetane may provide the corresponding heteracyclopropane regardless of the heteroatoms.

Transition metal-free: N -fluoroalkylation of amines using cyanurate activated fluoroalcohols

A novel and highly efficient method for N-fluoroalkylation of amines using 2,4,6-tris(fluoroalkoxy)-1,3,5-triazines was developed. This simple approach allowed the N-fluoroalkylation of amines under fast, mild and efficient reaction conditions, without using a transition metal as a catalyst.

A potential intermediate for the aza-Corey-Chaykovsky reaction: Synthesis, structure, and thermolysis of a pentacoordinate 1,2-thiazetidine 1-oxide

Thermolysis of a pentacoordinate 1λ6,2-thiazetidine, which was synthesized for the first time and characterized by X-ray crystallographic analysis, gave the corresponding aziridine and a cyclic sulfinate almost quantitatively. The potential intermediacy of a 1λ6,2-thiazetidine was suggested in the aza-Corey-Chaykovsky reaction.

REDUCTIVE DEFLUORINATION OF HEXAFLUOROACETONE ANIL

Hexafluoroacetone anil smoothly adds methyllithium at the C=N bond but undergoes reductive defluorination upon the action of Grignard reagents or metallic zinc to give 2-phenylaminopentafluoropropylene.

BIS(1-TRIFLUOROMETHYL-2,2,2-TRIFLUOROETHOXY)TRIPHENYLPHOSPHORANE. A NEW ROUTE TO TRIFLUOROMETHYLATED HETEROCYCLES

Bis(1-trifluoromethyl-2,2,2-trifluoroethoxy)triphenylphosphorane(1) readily reacted with anilines to form N-hexafluoroisopropylated products (2).By the dehydrofluorination of 2,2-arylamino-1,1,3,3,3-pentafluoropropenes(3) were obtained.Furthermore, when a