334866-56-7Relevant academic research and scientific papers
Synthesis and thermolysis of the novel ring systems containing nitrogen and tetracoordinate selenium
Kano, Naokazu,Daicho, Yuya,Nakanishi, Nobuhito,Kawashima, Takayuki
, p. 259 - 262 (2001)
Oxidation of β-aminoalkyl selenides bearing the Martin ligand with mCPBA gave tetracoordinate 1,2-selenazetidines or a tetracoordinate 1,2,5-oxaselenazolidine as stable colorless crystals. The thermolysis of 1,2-selenazetidines afforded the corresponding
Synthesis, crystal structure, and thermolysis of the first tetracoordinate 1λ4,2-selenazetidines: Aziridine formation reaction from a four-membered heterocycle bearing highly coordinate selenium
Kano, Naokazu,Daicho, Yuya,Nakanishi, Nobuhito,Kawashima, Takayuki
, p. 691 - 693 (2007/10/03)
Equation presented The first tetracoordinate 1λ4,2-selenazetidines were synthesized by taking advantage of the Martin ligand and characterized by X-ray crystallographic analysis. The selenazetidines gave the corresponding aziridine and the cyclic selenenate on their thermolysis, which indicates the possibiliy that a highly coordinate 1,2-heterachalcogenetane may provide the corresponding heteracyclopropane regardless of the heteroatoms.
