173602-42-1

Basic information

• Product Name: (3R,4R,5S,6R)-6-Dimethoxymethyl-3-methyl-4,5-bis-trifluoromethanesulfonyloxy-[1,2]oxazinane-2-carboxylic acid benzyl ester
• Synonyms: (3R,4R,5S,6R)-6-Dimethoxymethyl-3-methyl-4,5-bis-trifluoromethanesulfonyloxy-[1,2]oxazinane-2-carboxylic acid benzyl ester
• CAS NO: 173602-42-1
• Molecular Weight: 605.487
• Mol File: 173602-42-1.mol

Chemical Properties

• CAS DataBase Reference: (3R,4R,5S,6R)-6-Dimethoxymethyl-3-methyl-4,5-bis-trifluoromethanesulfonyloxy-[1,2]oxazinane-2-carboxylic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,4R,5S,6R)-6-Dimethoxymethyl-3-methyl-4,5-bis-trifluoromethanesulfonyloxy-[1,2]oxazinane-2-carboxylic acid benzyl ester(173602-42-1)
• EPA Substance Registry System: (3R,4R,5S,6R)-6-Dimethoxymethyl-3-methyl-4,5-bis-trifluoromethanesulfonyloxy-[1,2]oxazinane-2-carboxylic acid benzyl ester(173602-42-1)

Safety Data

• Hazardous Substances Data: 173602-42-1(Hazardous Substances Data)

Upstream product

• 358-23-6 trifluoromethylsulfonic anhydride 
• 173829-12-4 (3R,4R,5R,6R)-6-Dimethoxymethyl-4,5-dihydroxy-3-methyl-[1,2]oxazinane-2-carboxylic acid benzyl ester 

Downstream Products

• 135395-47-0 1,5,6-trideoxy-1,5-imino-D-galactitol 
• 173933-53-4 (3R,4S,5S,6R)-6-Dimethoxymethyl-4,5-dihydroxy-3-methyl-[1,2]oxazinane-2-carboxylic acid benzyl ester 

Relevant articles and documents

6-Deoxy-nojirimycin and 6-deoxy-gulo-nojirimycin in the racemic and D-series, D-fuco-nojirimycin and their 1-deoxyderivatives via hetero-Diels-Alder cycloadditions

Nucleophilic ring opening of the cyclic sulfates (±)-9c and D-9c and of the epoxide (±)-13, or double substitution of the bis-triflate D-10 (derived from the Diels-Alder adduct of hexodienal dimethylacetal to achiral or enantiomerically pure nitroso-derivatives) led to 6-deoxy-nojirimycin and 6-deoxy-gulo-nojirimycin in the racemic and D-series, to D-fuco-nojirimycin and to their 1-deoxyderivatives via their crystalline 1-deoxy-1-sulfonic acid derivatives (sulfite adducts). 6-Deoxy-nojirimycin and its isomers are mixtures of α- and β-anomers and of the corresponding imine.