173933-53-4

Upstream product

• 197567-75-2 (3aS,4R,7R,7aR)-4-Dimethoxymethyl-7-methyl-2,2-dioxo-tetrahydro-1,3,5-trioxa-2λ⁶-thia-6-aza-indene-6-carboxylic acid benzyl ester 
• 173602-42-1 (3R,4R,5S,6R)-6-Dimethoxymethyl-3-methyl-4,5-bis-trifluoromethanesulfonyloxy-[1,2]oxazinane-2-carboxylic acid benzyl ester 

Downstream Products

• 264234-38-0 benzyl (3R)-c-4,c-5-isopropylidenedioxy-c-6-dimethoxymethyl-r-3-methyl-1,2-oxazane-2-carboxylate 
• 135395-47-0 1,5,6-trideoxy-1,5-imino-D-galactitol 
• 264234-47-1 5-(benzyloxycarbonylamino)-3,4-O-isopropylidene-2-O-methanesulfonyl-5,6-dideoxy-D-fucose dimethylacetal 
• 264234-46-0 5-(benzyloxycarbonylamino)-3,4-O-isopropylidene-5,6-dideoxy-D-fucose dimethylacetal 
• 264234-41-5 2,5-(benzyloxycarbonylimino)-3,4-O-isopropylidene-2,5,6-trideoxy-D-talose dimethylacetal 
• 264234-49-3 2,5-(benzyloxycarbonylimino)-3,4-O-isopropylidene-2,5,6-trideoxy-D-talitol 
• 264234-43-7 2,5-(benzyloxycarbonylimino)-2,5,6-trideoxy-D-talitol 
• 264234-48-2 2,5-(benzyloxycarbonylimino)-3,4-O-isopropylidene-2,5,6-trideoxy-D-talose 
• 637771-89-2 (1R,2S,3R,4R)-1-methyl-2,3-diol-4-hydroxymethyl pyrrolidine 

Relevant academic research and scientific papers

6-Deoxy-nojirimycin and 6-deoxy-gulo-nojirimycin in the racemic and D-series, D-fuco-nojirimycin and their 1-deoxyderivatives via hetero-Diels-Alder cycloadditions

Nucleophilic ring opening of the cyclic sulfates (±)-9c and D-9c and of the epoxide (±)-13, or double substitution of the bis-triflate D-10 (derived from the Diels-Alder adduct of hexodienal dimethylacetal to achiral or enantiomerically pure nitroso-derivatives) led to 6-deoxy-nojirimycin and 6-deoxy-gulo-nojirimycin in the racemic and D-series, to D-fuco-nojirimycin and to their 1-deoxyderivatives via their crystalline 1-deoxy-1-sulfonic acid derivatives (sulfite adducts). 6-Deoxy-nojirimycin and its isomers are mixtures of α- and β-anomers and of the corresponding imine.