173604-32-5

Basic information

• Product Name: 2-Oxazolidinone, 4-(hydroxydiphenylmethyl)-, (S)-
• CAS NO: 173604-32-5
• Molecular Formula: C16H15NO3
• Molecular Weight: 269.3
• Mol File: 173604-32-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Oxazolidinone, 4-(hydroxydiphenylmethyl)-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Oxazolidinone, 4-(hydroxydiphenylmethyl)-, (S)-(173604-32-5)
• EPA Substance Registry System: 2-Oxazolidinone, 4-(hydroxydiphenylmethyl)-, (S)-(173604-32-5)

Safety Data

• Hazardous Substances Data: 173604-32-5(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 
• 96751-61-0 (S)-4-methoxycarbonyl-oxazolidin-2-one 
• 100-58-3 phenylmagnesium bromide 

Downstream Products

• 173604-34-7 (R)-4-Benzhydryl-2-oxo-oxazolidine-3-carboxylic acid tert-butyl ester 
• 155836-48-9 tert-butyl [(2R)-3-hydroxy-1,1-diphenylpropan-2-yl]carbamate 
• 143060-31-5 N-(tert-butoxycarbonyl)-3,3-diphenyl-D-alanine 
• 173604-33-6 (4R)-4-(diphenylmethyl)-2-oxazolidinone 

Relevant articles and documents

A ferrocenyl-DHIPOH/Cu(OAc)2 complex for diastereo- and enantioselective catalysis of the 1,4-addition of glycine derivatives to alkylidene malonates

A planar chiral ferrocene derivative Fc-DHIPOH served as an excellent N,O- chiral ligand for asymmetric copper catalyzed 1,4-addition of glycine derivatives to alkylidene malonates. The corresponding 1,4-adducts were obtained in high yields with excellent enantioselectivities up to 95% ee.

Synthesis of N-BOC-D-Diphenylalanine from L-Serine Methyl Ester Hydrochloride

A convenient six step synthesis of N-BOC-D-diphenylalanine from L-serine methyl ester hydrochloride is described.The preparation of a novel chiral auxiliary, an oxazolidinone derived from D-diphenylalaninol, is also described.