173726-42-6Relevant articles and documents
Triphenylphosphine-Based Covalent Organic Frameworks and Heterogeneous Rh-P-COFs Catalysts
Liu, Yubing,Dikhtiarenko, Alla,Xu, Naizhang,Sun, Jiawei,Tang, Jie,Wang, Kaiqiang,Xu, Bolian,Tong, Qing,Heeres, Hero Jan,He, Songbo,Gascon, Jorge,Fan, Yining
, p. 12134 - 12139 (2020/09/01)
The synthesis of phosphine-based functional covalent organic frameworks (COFs) has attracted great attention recently. Herein, we present two examples of triphenylphosphine-based COFs (termed P-COFs) with well-defined crystalline structures, high specific surface areas, and good thermal stability. Furthermore, rhodium catalysts with these P-COFs as support material show high turnover frequency for the hydroformylation of olefins, as well as excellent recycling performance. This work not only extends the phosphine-based COF family, but also demonstrates their application in immobilizing homogeneous metal-based (e.g., Rh-phosphine) catalysts for application in heterogeneous catalysis.