173789-78-1

Basic information

• Product Name: trans-bis(4-methylbenzenecarboselenoato)bis(triethylphosphine)palladium(II)
• CAS NO: 173789-78-1
• Molecular Weight: 738.944
• Mol File: 173789-78-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-bis(4-methylbenzenecarboselenoato)bis(triethylphosphine)palladium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: trans-bis(4-methylbenzenecarboselenoato)bis(triethylphosphine)palladium(II)(173789-78-1)
• EPA Substance Registry System: trans-bis(4-methylbenzenecarboselenoato)bis(triethylphosphine)palladium(II)(173789-78-1)

Safety Data

• Hazardous Substances Data: 173789-78-1(Hazardous Substances Data)

Upstream product

• 28425-04-9 dichlorobis(triethylphosphine)palladium(II) 
• 137768-63-9 O-trimethylsilyl 4-methylbenzenecarboselenoate 

Relevant articles and documents

Preparation of bis(phosphine)bis(selenocarboxylato)-nickel(II), -palladium(II) and -platinum(II) complexes and their crystal structure analysis

A series of bis(triorganophosphine)bis(selenocarboxylato)-nickel(II) 3, -palladium(II) 4 and -platinum(II) 5 complexes have been sythesised from the reaction of sodium selenocarboxylates 1 or O-silyl selenocarboxylates 2 with the corresponding bis(phosphine)metal dichloride in good to high yields and have been characterized by 1H, 13C, 31P and 77Se NMR spectroscopy and elemental analysis.Additionally (M = Ni 3d, Pd 4d or Pt 5b) have been crystallographically characterized and reveal four-co-ordinate planar structures with each of the two selenocarboxylate and phosphine ligands lying trans.The carbon-oxygen bond lengths of the selenocarboxylate ligand of 3d, 4d and 5d show values typical of a carbon-oxygen double bond; co-ordination of the carbonyl oxygen to the metal is not observed.