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28425-04-9

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28425-04-9 Usage

Chemical Properties

Yellow powder

Uses

trans-Dichlorobis(triethylphosphine)palladium(II) is used in coupling of C-C bonds. It is also used as pharmaceutical and organic Intermediates.

Check Digit Verification of cas no

The CAS Registry Mumber 28425-04-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,8,4,2 and 5 respectively; the second part has 2 digits, 0 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 28425-04:
(7*2)+(6*8)+(5*4)+(4*2)+(3*5)+(2*0)+(1*4)=109
109 % 10 = 9
So 28425-04-9 is a valid CAS Registry Number.
InChI:InChI=1/2C6H15P.2ClH.Pd/c2*1-4-7(5-2)6-3;;;/h2*4-6H2,1-3H3;2*1H;/q;;;;+2/p-2

28425-04-9 Well-known Company Product Price

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  • Alfa Aesar

  • (39823)  trans-Dichlorobis(triethylphosphine)palladium(II)   

  • 28425-04-9

  • 0.25g

  • 376.0CNY

  • Detail
  • Alfa Aesar

  • (39823)  trans-Dichlorobis(triethylphosphine)palladium(II)   

  • 28425-04-9

  • 1g

  • 1360.0CNY

  • Detail
  • Alfa Aesar

  • (39823)  trans-Dichlorobis(triethylphosphine)palladium(II)   

  • 28425-04-9

  • 5g

  • 6338.0CNY

  • Detail

28425-04-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name dichloropalladium,triethylphosphane

1.2 Other means of identification

Product number -
Other names Bis(triethylphosphine)palladium dichloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:28425-04-9 SDS

28425-04-9Relevant articles and documents

Self-assembly of metal-organic hybrid nanoscopic rectangles

Ghosh, Sushobhan,Mukherjee, Partha Sarathi

, p. 2542 - 2546 (2007)

The combination of an amide containing a linear ligand (L1) and an organometallic molecular "clip" (clip-1) leads to the self-assembly of a Pt4 nanoscopic framework representing the first example of a Pt-based molecular rectangle (rectangle-1)

3-Dimethylaminopropyl chalcogenolate complexes of palladium(II): Syntheses and characterization, including the crystal structures of [Pd(OAc)(ECH 2CH2CH2NMe2)]2· H2O (E = S, Se) and [PdCl(TeCH2CH2CH 2NMe2)]2

Dey, Sandip,Jain, Vimal K.,Varghese, Babu,Schurr, Thilo,Niemeyer, Mark,Kaim, Wolfgang,Butcher, Ray J.

, p. 1449 - 1457 (2008/10/09)

The reactions of the sodium salts of 3-dimethylamino-1- propylchalcogenolates, prepared by sodium borohydride reduction of (Me 2NCH2CH2CH2E)2 in methanol, with Na2PdCl4 yielded homoleptic [Pd(ECH 2CH2CH2NMe2)2] 6 (1) (E = S (1a); Se (1b); Te (1c)). When treated with [Pd(OAc) 2]3 or Na2PdCl4, compounds 1 readily gave binuclear redistribution products [PdX(ECH2CH 2CH2NMe2)]2 where X = OAc (2) (E = S (2a); Se (2b); or Cl (3)) (E = S (3a); Se (3b); Te (3c)), respectively. The terminal acetate/chloride ligands in 2b/3b can be substituted by other ionic ligands like PhSe-. The complexes were characterized by elemental analysis, UV-Vis, IR and NMR spectroscopy. The structures of 2a, 2b and 3c were established by X-ray crystallography. Each molecule has a dimeric structure in which there are two chalcogenolate bridges from the chelating 3-dimethylamino-1-propylchalcogenolate ligands. On pyrolysis, compound 2b affords Pd17Se15.

Structure and reactivity of (η3-indolylmethyl)palladium complexes generated by the reaction of organopalladium complexes with o-alkenylphenyl isocyanide

Onitsuka, Kiyotaka,Yamamoto, Mari,Suzuki, Shinobu,Takahashi, Shigetoshi

, p. 581 - 583 (2008/10/08)

Structure and reactivity of (η3-Indolylmethyl)palladium complexes generated by the reaction of organopalladium complexes with o-alkenylphenyl isocyanide were analyzed. The reaction of methylpalladium complexes with o-alkenylphenyl isocyanides r

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