174094-68-9Relevant academic research and scientific papers
Phosphine-participated formation and crystal structures of nickel complexes with 2-sulfanylphenol and phosphine ligands
Chen, Zhong Ning,Kang, Bei Sheng,Lin, Zhang,Wu, Bo Mu,Zhou, Zhong Yuan,Mak, Thomas C. W.,Chen, Chang Neng,Liu, Qiu Tian
, p. 177 - 181 (1996)
Neutral tri- and mono-nuclear complexes [Ni3(OC6H4S)2(HOC6H 4S)2(PBun3) 2]·2EtOH 1 and [Ni(OC6H4S)-(PMe2Ph)2] 2 of 2-sulfanylphenol were obtained in the presence of a phosphine in EtOH solutions, and their crystal structures determined. Complex 1 is made up of three nickel ions chelated and bridged by two OC6H4S2- dianions in ObSt fashion and two HOC6H4S- monoanions in HOtSb, fashion, where the central nickel(II) atom has an elongated octahedral geometry whereas the two at the sides have square-planar surroundings. In 2 the nickel(II) atom is located in a square-planar environment, chelated by a OC6H4S2- dianion in OtSt mode. Complex 1 is paramagnetic and its magnetic behaviour is explained by single-ion anisotropy.
