Phosphine-participated formation and crystal structures of nickel complexes with 2-sulfanylphenol and phosphine ligands

DOI: 10.1039/dt9960000177

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 177 - 181 (1996)

Update date:2022-07-31

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Authors:

Chen, Zhong Ning

Kang, Bei Sheng

Lin, Zhang

Wu, Bo Mu

Zhou, Zhong Yuan

Mak, Thomas C. W.

Chen, Chang Neng

Liu, Qiu Tian

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Article abstract of DOI:10.1039/dt9960000177

Neutral tri- and mono-nuclear complexes [Ni₃(OC₆H₄S)₂(HOC₆H ₄S)₂(PBuⁿ₃) ₂]·2EtOH 1 and [Ni(OC₆H₄S)-(PMe₂Ph)₂] 2 of 2-sulfanylphenol were obtained in the presence of a phosphine in EtOH solutions, and their crystal structures determined. Complex 1 is made up of three nickel ions chelated and bridged by two OC₆H₄S^2- dianions in O_bS_t fashion and two HOC₆H₄S^- monoanions in HO_tS^b, fashion, where the central nickel(II) atom has an elongated octahedral geometry whereas the two at the sides have square-planar surroundings. In 2 the nickel(II) atom is located in a square-planar environment, chelated by a OC₆H₄S^2- dianion in O_tS_t mode. Complex 1 is paramagnetic and its magnetic behaviour is explained by single-ion anisotropy.

Full text of DOI:10.1039/dt9960000177

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