Journal of the Chemical Society, Dalton Transactions p. 177 - 181 (1996)
Update date:2022-07-31
Topics:
Chen, Zhong Ning
Kang, Bei Sheng
Lin, Zhang
Wu, Bo Mu
Zhou, Zhong Yuan
Mak, Thomas C. W.
Chen, Chang Neng
Liu, Qiu Tian
Neutral tri- and mono-nuclear complexes [Ni3(OC6H4S)2(HOC6H 4S)2(PBun3) 2]·2EtOH 1 and [Ni(OC6H4S)-(PMe2Ph)2] 2 of 2-sulfanylphenol were obtained in the presence of a phosphine in EtOH solutions, and their crystal structures determined. Complex 1 is made up of three nickel ions chelated and bridged by two OC6H4S2- dianions in ObSt fashion and two HOC6H4S- monoanions in HOtSb, fashion, where the central nickel(II) atom has an elongated octahedral geometry whereas the two at the sides have square-planar surroundings. In 2 the nickel(II) atom is located in a square-planar environment, chelated by a OC6H4S2- dianion in OtSt mode. Complex 1 is paramagnetic and its magnetic behaviour is explained by single-ion anisotropy.
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