174094-72-5

Upstream product

• 544-16-1 n-Butyl nitrite 
• 82108-96-1 dichloro(α-hydroxyiminopropiophenone)(α-hydroxyiminopropiophenonato)ruthenium(III) 
• 7632-00-0 sodium nitrite 

Downstream Products

• 174094-76-9 K⁽¹⁺⁾*Ru((CH₃CO)2CNO)((CH₃CO)2CH)(C₉H₈NO₂)^(1-)=K[RuC₁₉H₂₁N₂O₇] 

Relevant academic research and scientific papers

Synthesis, characterization and reactivity studies of some electrophilic mono- and binuclear nitrosyls of ruthenium(II) containing ketoximates

The reaction of [RuX2(HL)(L)] (2) [X = Cl or Br; HL (1) = PhC(O)C( = NOH)Ph (HL1) or PhC(O)C(=NOH)Me (HL2)] with BuONO affords mononuclear [RuX(NO)L21] (3) or binuclear [RuX2(NO)L2]2 (4) nitrosyls depending on L; 3 and 4 are also obtainable by reacting 2 with NaNO2 in the presence of hydrochloric acid. Molecular weight determinations are in full consonance with mono- and binuclear formulations. Both 3 and 4 are electroactive and reductions characteristic of mono- and binuclear compositions are observable on the negative side of SCE. They react smoothly with acetylacetone (acacH) in presence of K2CO3 affording K[Ru(acamo)L21] (6) and K[Ru(acac)(acamo)L2] (7) [acamo is deprotonated CH3C(= O)C(=NOH)[C(=O)CH3] respectively.