174153-82-3Relevant academic research and scientific papers
Anomalies in the stereoselectivity of the petasis reaction using styrenyl boronic acids
Churches, Quentin I.,Johnson, James K.,Fifer, Nathan L.,Hutton, Craig A.
scheme or table, p. 62 - 67 (2011/10/05)
The Petasis three-component coupling reaction of N-benzylphenylglycinol, glyoxylic acid, and styrenylboronic acids allows for the efficient synthesis of functionalized homoarylalanine derivatives. The reactions were shown to proceed in high yield but low selectivity, regardless of the nature of the substituent on the styrenylboronic acid component. Anomalies in the stereoselectivity of these reactions compared with previously reported results have been traced to the source of the organoboronic acid. Asymmetric dihydroxylation of the unsaturated amino acid derivatives enables a highly efficient route to dihydroxyhomoarylalanine derivatives. CSIRO 2011.
A Novel and Efficient Route to (E)-Alk-1-enyl Boronic Acid Derivatives from (E)-1-(Trimethylsilyl)alk-1-enes and a Formal Suzuki-Miyaura Cross-coupling Reaction starting with Vinylsilanes
Farinola, Gianluca M.,Fiandanese, Vito,Mazzone, Luigia,Naso, Francesco
, p. 2523 - 2524 (2007/10/03)
A novel and highly efficient conversion of vinylsilanes into vinyl boronates is described together with their Suzuki-Miyaura cross-coupling reaction, performed without isolating the intermediate resulting from borodesilylation.
