174176-78-4

Upstream product

• 174176-77-3 (1S,5S,8R)-8-(1',3'-dithianyl-2')methyl-2-oxabicyclo[3,2,1]octan-3-one 
• 53320-19-7 (1S,3RS,5R,6S)-3-methoxy-6-methoxycarbonylmethyl-2-oxabicyclo<3.3.0>octane 
• 245741-72-4 Triphenyl-(3-phenylselanyl-propylidene)-λ⁵-phosphane 

Relevant academic research and scientific papers

Synthesis of both the enantiomers of methyl cis-(Z)-dehydrojasmonate, principal note for the scent of Cymbidium goeringii, to determine the absolute configuration

Both the enantiomers of methyl cis-(Z)-dehydrojasmonate 1 were prepared from the common intermediate 4 of our jasmonoid synthesis. (2S,3R)-1 was proved to be identical with the naturally occurring enantiomer by GC analysis using a chiral stationary phase.