17420-02-9

Basic information

• Product Name: N-Sulfinyl-2,6-dimethylaniline
• Synonyms: 2,6-Dimethyl-N-sulfinylaniline;N-Sulfinyl-2,6-dimethylaniline;N-Sulfinyl-2,6-xylidine
• CAS NO: 17420-02-9
• Molecular Formula: C₈H₉NOS
• Molecular Weight: 167.23
• Mol File: 17420-02-9.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-Sulfinyl-2,6-dimethylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-Sulfinyl-2,6-dimethylaniline(17420-02-9)
• EPA Substance Registry System: N-Sulfinyl-2,6-dimethylaniline(17420-02-9)

Safety Data

• Hazardous Substances Data: 17420-02-9(Hazardous Substances Data)

Upstream product

• 87-62-7 2,6-dimethylaniline 
• 69563-03-7 N-(2,6-dimethylphenyl)-N-trimethylsilylamine 

Downstream Products

• 70376-07-7 3-(2,6-dimethyl-phenyl)-2-oxo-5,6-diphenyl-2,3-dihydro-2λ⁴-[1,2,3]oxathiazin-4-one 
• 81720-47-0 3,5-dimethyl-2-(2,6-dimethylphenyl)-1,4-dithia-2-aza-3,5-diborolidine 
• 1520120-41-5 2-(2,6-dimethylphenyl)-1-ethyl-1-oxo-1λ⁶-thia-2,6-diazacyclohex-6-en-3-one 
• 1520120-11-9 3-{[(2,6-dimethylanilino)ethyloxo-1λ⁶-sulfanylidene]amino}propanoic acid 
• 1520119-85-0 ethyl 3-{[(2,6-dimethylanilino)ethyloxo-1λ⁶-sulfanylidene]amino}propanoate 
• 1520119-61-2 N-(2,6-dimethylphenyl)ethanesulfinamide 
• 123394-93-4 1-(2,6-dimethylphenyl)-3-trimethylstannyl-1,3-diaza-2-thiaallene 
• 20380-32-9 octamethyl-(1rH,2cH,5cH,6cH)-tricyclo[4.2.0.0^2,5]octa-3,7-diene 
• 86803-59-0 3-(2,6-dimethylphenyl)-1,4,5,6-tetramethyl-2-thia-3-azabicyclo<2.20>hex-5-ene 2-dioxide 
• 87-62-7 2,6-dimethylaniline 
• 100073-09-4 1-(2,6-dimethylphenyl)-3-trimethylsilyl-1,3-diaza-2-thiaallene 

Relevant articles and documents

Ring-Closing Olefin Metathesis Catalyzed by Well-Defined Vanadium Alkylidene Complexes

Vanadium-based catalysts have shown activity and selectivity in ring-opening metathesis polymerization of strained cyclic olefins comparable to those of Ru, Mo, and W catalysts. However, the application of V alkylidenes in routine organic synthesis is limited. Here, we present the first example of ring-closing olefin metathesis catalyzed by well-defined V chloride alkylidene phosphine complexes. The developed catalysts exhibit tolerance to various functional groups, such as an ether, an ester, a tertiary amide, a tertiary amine, and a sulfonamide. The size and electron-donating properties of the imido group and the phosphine play a crucial role in the stability of active intermediates. Reactions with ethylene and olefins suggest that both β-hydride elimination of the metallacyclobutene and bimolecular decomposition are responsible for catalyst degradation.

A New Synthesis of N-Sulfinylamines by Sulfinylation of N-Trimethylsilylamines using Sulfur Dioxide

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