174276-79-0Relevant academic research and scientific papers
Mutual Isomerization of η1-Allenyl and η1-Propargyl Complexes of Platinum via a Five-coordinate η3-Allenyl/propargyl Intermediate
Ogoshi, Sensuke,Fukunishi, Yoshiaki,Tsutumi, Ken,Kurosawa, Hideo
, p. 2485 - 2486 (1995)
The reversible spontaneous isomerization between η1-allenyl and η1-propargylplatinum complexes is reported, which is suggested to proceed via pseudorotation of a five-coordinate η3-allenyl/propargyl intermediate.
Mechanistic studies on mutual isomerization of propargyl- and allenylplatinum (II) complexes
Ogoshi, Sensuke,Fukunishi, Yoshiaki,Tsutsumi, Ken,Kurosawa, Hideo
, p. 9 - 15 (2008/10/08)
When heated in benzene, phenyl-substituted propargylplatinum(II) complexes, trans-Pt(CH2C≡CPh)(X)(PPh3)2 (2) (X = Cl, Br, I), isomerized gradually to the more stable allenyl isomers, trans-Pt(CPh=C=CH2) (X) (PPh
