174316-50-8

Basic information

• Product Name: 3,5-Cyclohexadiene-1,2-dione,4-(butylamino)-5-methoxy-(9CI)
• Synonyms: 3,5-Cyclohexadiene-1,2-dione,4-(butylamino)-5-methoxy-(9CI)
• CAS NO: 174316-50-8
• Molecular Formula: C11H15NO3
• Molecular Weight: 209.2417
• Product Categories: ALCOHOL
• Mol File: 174316-50-8.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3,5-Cyclohexadiene-1,2-dione,4-(butylamino)-5-methoxy-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-Cyclohexadiene-1,2-dione,4-(butylamino)-5-methoxy-(9CI)(174316-50-8)
• EPA Substance Registry System: 3,5-Cyclohexadiene-1,2-dione,4-(butylamino)-5-methoxy-(9CI)(174316-50-8)

Safety Data

• Hazardous Substances Data: 174316-50-8(Hazardous Substances Data)

Upstream product

• 99814-64-9 4-methoxy-5-(4-methoxyphenoxy)cyclohexa-3,5-diene-1,2-dione 
• 109-73-9 N-butylamine 
• 150-76-5 4-methoxy-phenol 
• 179805-65-3 4-(Butyl-methyl-amino)-5-methoxy-[1,2]benzoquinone 

Relevant articles and documents

Reactions of 4-dialkylamino-5-methoxy-1,2-benzoquinones in acidic media: Selective C-alkylation or N-dealkylation

4-(N-methyl-alkylamino)-5-methoxy-1,2-benzoquinones 3, for which N-alkyl group R1 can give rise to a stabilized carbonium ion, undergo selective acid-catalyzed rearrangements to 3-alkylated-1,2-benzoquinones 4. Aziridino- quinone 10c gives rise to the heterobicyclic 1,2-benzoquinone 11. When R1 does not contain groups capable of stabilizing a positive charge, efficient and selective N-dealkylations occur. The mechanisms of these reactions are discussed.