17432-62-1Relevant academic research and scientific papers
Gold complexes of bis-indazole-derived N-Heterocyclic carbene: Synthesis, structural characterizations, and catalysis
Zhang, Hua,Xu, Ting,Li, Dongdong,Cheng, Tao,Chen, Jing,Zhou, Yang
, (2021)
A novel series of bis Indy-NHC gold complexes have been developed and investigated via a mild Ag-carbene transfer route. The obtained complexes were characterized by NMR spectroscopy and X-ray diffraction analysis. The catalytic property of these gold complexes was further evaluated in the oxidation of benzylic. The gold complex E1 showed a high catalytic activity in the oxidation of various benzylic substrates, resulting in the corresponding carbonyl compounds with excellent yields using TBHP as oxidant.
Microwave-assisted molybdenum-catalyzed reductive cyclization of o -nitrobenzylidene amines to 2-Aryl-2 H -indazoles
Moustafa, Ahmed H.,Malakar, Chandi C.,Aljaar, Nayyef,Merisor, Elena,Conrad, Jürgen,Beifuss, Uwe
supporting information, p. 1573 - 1577 (2013/08/23)
The reductive cyclization of o-nitrobenzylidene amines under microwave conditions employing MoO2Cl2(dmf)2 as catalyst and Ph3P as reducing agent delivers 2-aryl-2H-indazoles with yields ranging from 61-92%. Georg Thieme Verlag Stuttgart. New York.
