174358-48-6Relevant articles and documents
Unexpected oxadi-π-methane rearrangement of β,γ-unsaturated aldehydes
Armesto, Diego,Ortiz, Maria J.,Romano, Santiago,Agarrabeitia, Antonia R.,Gallego, Mar G.,Ramos, Ana
, p. 1459 - 1466 (2007/10/03)
The oxadi-π-methane rearrangement (ODPM) is considered to represent the normal photochemical behavior of β,γ-unsaturated ketones in the triplet excited π,π* state. However, the usual photoreactivity reported for the majority of β,γ-unsaturated aldehydes i