174362-09-5

Basic information

• Product Name: ethyl 3-cyano-2-(triphenylphosphoranylidene)propanoate
• Synonyms: ethyl 3-cyano-2-(triphenylphosphoranylidene)propanoate
• CAS NO: 174362-09-5
• Molecular Weight: 387.418
• Mol File: 174362-09-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: ethyl 3-cyano-2-(triphenylphosphoranylidene)propanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 3-cyano-2-(triphenylphosphoranylidene)propanoate(174362-09-5)
• EPA Substance Registry System: ethyl 3-cyano-2-(triphenylphosphoranylidene)propanoate(174362-09-5)

Safety Data

• Hazardous Substances Data: 174362-09-5(Hazardous Substances Data)

Upstream product

• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 
• 590-17-0 cyanomethyl bromide 

Downstream Products

• 1386860-02-1 ethyl 2-amino-7-{4-[(ethoxycarbonyl)amino]phenyl}-3H-1-benzazepine-4-carboxylate 
• 1386859-78-4 ethyl 2-amino-7-[4-(2-oxopyrrolidin-1-yl)phenyl]-3H-1-benzazepine-4-carboxylate 
• 1384958-63-7 (E)-ethyl 3-(5-bromo-2-nitrophenyl)-2-(cyanomethyl)acrylate 
• 1384958-42-2 (E)-ethyl 9-(4-(pyrrolidine-1-carbonyl)phenyl)-2,4-dihydro-1H-benzo[f]imidazo[1,2-a]azepine-5-carboxylate 
• 1268163-65-0 (1E,4E)-ethyl 2-(tert-butoxycarbonylamino)-8-(3-cyanophenyl)-3H-benzo[b]azepine-4-carboxylate 
• 1268163-42-3 C₁₃H₁₁BrN₂O₄ 
• 926927-55-1 2-[1-(4-bromo-2-nitrophenyl)-(E)-methylidene]-3-cyanopropionic acid ethyl ester 
• 29708-10-9 (E)-ethyl 3-(4-bromo-2-nitrophenyl)-2-(cyanomethyl)acrylate 
• 190778-70-2 (E)-5-Benzyloxy-3-(benzyl-phenyl-amino)-2-cyanomethyl-pent-2-enoic acid ethyl ester 
• 190778-74-6 (E)-3-(Benzyl-phenyl-amino)-2-cyanomethyl-4-(2-methyl-[1,3]dioxolan-2-yl)-but-2-enoic acid ethyl ester 
• 174362-12-0 (E)-5-Benzyloxy-3-(benzyl-phenyl-amino)-2-cyanomethyl-pent-2-enoic acid ethyl ester 
• 174362-06-2 (E)-3-(Benzyl-phenyl-amino)-2-cyanomethyl-4-(2-methyl-[1,3]dioxolan-2-yl)-but-2-enoic acid ethyl ester 
• 174362-11-9 ethyl 2-cyanomethyl-5-benzyloxy-penta-2,3-dienoate 

Relevant articles and documents

New synthetic routes to Z-shape functionalized perylenes

Z-shape (1,2,7,8-tetrasubstituted) perylene derivatives are novel chromophores with great potential in various applications. Yet, the synthetic entry into this class of molecules is hitherto quite limited. In this communication, the synthesis of a series

Engaging Allene-Derived Zwitterions in an Unprecedented Mode of Asymmetric [3+2]-Annulation Reaction

Catalytic addition of chiral phosphine, that is, (R)- or (S)-SITCP, to an α-substituted allene ester generated a zwitterionic dipole. Under optimized reaction conditions, this dipole could engage isatine-derived N-Boc-ketimines in a novel mode of [3+2] an

Synthesis of β-enaminoesters and lactams by Michael addition of N- benzylaniline to new allenic esters and lactams

The synthesis of original allenic lactams 2 and allenic esters 5 is presented and their Michael condensation with N-benzylaniline described.