174460-89-0Relevant academic research and scientific papers
Fe-promoted cross coupling of homobenzylic methyl ethers with Grignard reagents via sp3 C-O bond cleavage
Luo, Shuang,Yu, Da-Gang,Zhu, Ru-Yi,Wang, Xin,Wang, Lei,Shi, Zhang-Jie
supporting information, p. 7794 - 7796 (2013/09/02)
The first iron-catalyzed formal cross coupling of homobenzylic methyl ethers with alkyl Grignard reagents is realized. The reaction is proposed to proceed through a sequence of dehydroalkoxylation to form the vinyl-intermediate, followed by Fe-catalyzed selective carbometalation to form a benzylic Grignard reagent.
Easy eco-friendly phenonium ion production from phenethyl alcohols in dimethyl carbonate
Barontini,Proietti Silvestri,Nardi,Bovicelli,Pari,Gallucci,Spezia,Righi
supporting information, p. 5004 - 5006 (2013/08/28)
An efficient and simple one-pot procedure for selective etherification of 2-aryl-ethylalcohols has been achieved through Amberlyst 15-catalyzed reaction in dimethyl carbonate (DMC). Moreover, the polymer catalyst could be recovered and reused with no effect on its activity. The reaction mechanism involves the formation of phenonium ion which has been demonstrated by a C-C bond forming reaction. Theoretical studies are in agreement with and thus explain experimental results.
Lipase-mediated Resolution of 2-Cyclohexen-1-ols as Chiral Building Blocks en route to Eburnane Alkaloids
Carrea, Giacomo,Danieli, Bruno,Palmisano, Giovanni,Riva, Sergio,Santagostino, Marco
, p. 775 - 784 (2007/10/02)
Lipase catalyzed esterification of several 2-cyclohexen-1-ols proceeds with excellent enantioselectivity leading to (S)-enantiomers as promising chiral building blocks en route to eburnane alkaloids.
