174813-81-1

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Basic information

Product Name: Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](mesitylene)
Synonyms: Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](mesitylene);Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](mesitylene);Chloro{[(1S,2S)-(+)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(Mesitylene)rutheniuM(II),90% RuCl[(S,S)-Tsdpen](Mesitylene);Chloro[[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido](mesitylene)ruthenium(II);[N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1,3,5-trimethylbenzene]-ruthenium;Chloro[(1S,2S)-N-(p-toluenesulfonyl)-1,2-diphenylethanediamine](mesitylene)ruthenium(II)
CAS NO:174813-81-1
Molecular Formula: C₃₀H₃₃ClN₂O₂RuS
Molecular Weight: 635.1588
EINECS: N/A
Product Categories: organometallic complex;Ru
Mol File: 174813-81-1.mol
Article Data: 1

Chemical Properties

Melting Point: 241-249°C
Boiling Point: N/A
Flash Point: N/A
Appearance: yellow to dark brown/solid
Density: N/A
Refractive Index: N/A
Storage Temp.: 2-8°C
Solubility: N/A
Sensitive: air sensitive
CAS DataBase Reference: Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](mesitylene)(CAS DataBase Reference)
NIST Chemistry Reference: Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](mesitylene)(174813-81-1)
EPA Substance Registry System: Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](mesitylene)(174813-81-1)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany: 2
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 174813-81-1(Hazardous Substances Data)

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Chloro-{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl]-(4-toluenesulfonyl)-amido}-(mesitylene)-ruthenium(II)
Cas No: 174813-81-1
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Chemwill Asia Co., Ltd.
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Cas No: 174813-81-1
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Chloro([(1S,2S)-(-)-2-Amino-1,2-diphenylethyl](4-toluenesulfonyl)amido)(mesitylene)ruthenium(II)
Cas No: 174813-81-1
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Dayang Chem (Hangzhou) Co.,Ltd.
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Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](mesitylene)
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Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](mesitylene)
Cas No: 174813-81-1
USD $ 2.0-2.0 / Kilogram
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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD
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Chloro{[(1S,2S)-(+)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(Mesitylene)rutheniuM(II), Min. 90% RuCl[(S,S)-Tsdpen](Mesitylene)
Cas No: 174813-81-1
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RuCl[(S,S)-Tsdpen](mesitylene)
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Hangzhou Fandachem Co.,Ltd
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Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), RuCl[(S,S)-Tsdpen](mesitylene)
Cas No: 174813-81-1
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HANGZHOU TIANYE CHEMICALS CO., LTD.
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Chloro(mesitylene)[(S,S)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II)
Cas No: 174813-81-1
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Chemsigma International Co.,Ltd.
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Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](mesitylene)
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ZHEJIANG JIUZHOU CHEM CO.,LTD
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174813-81-1 Usage

Reactions

Catalyst used in the asymmetric transfer hydrogenation of ketones using formic acid-triethylamine mixture.

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Check Digit Verification of cas no

The CAS Registry Mumber 174813-81-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,7,4,8,1 and 3 respectively; the second part has 2 digits, 8 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 174813-81:
(8*1)+(7*7)+(6*4)+(5*8)+(4*1)+(3*3)+(2*8)+(1*1)=151
151 % 10 = 1
So 174813-81-1 is a valid CAS Registry Number.

174813-81-1 Well-known Company Product Price

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(Code)Product description
CAS number
Packaging
Price
Detail

TCI America
(R0126) RuCl[(S,S)-Tsdpen](mesitylene) >90%(HPLC)
174813-81-1
200mg
450.00CNY
Detail

TCI America
(R0126) RuCl[(S,S)-Tsdpen](mesitylene) >90%(HPLC)
174813-81-1
1g
1,560.00CNY
Detail

Aldrich
(708674) RuCl[(S,S)-TsDPEN](mesitylene) 95%
174813-81-1
708674-100MG
290.16CNY
Detail

Aldrich
(708674) RuCl[(S,S)-TsDPEN](mesitylene) 95%
174813-81-1
708674-500MG
1,036.62CNY
Detail

174813-81-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name	Chloro(mesitylene)[(S,S)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II)

1.2 Other means of identification

Product number	-
Other names	[(S,S)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide]chloro(mesitylene)ruthenium(II)

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:174813-81-1 SDS

174813-81-1Upstream product

174813-81-1Downstream Products

174813-81-1Relevant articles and documents

Ruthenium(II)-catalyzed asymmetric transfer hydrogenation of ketones using a formic acid-triethylamine mixture

Fujii, Akio,Hashiguchi, Shohei,Uematsu, Nobuyuki,Ikariya, Takao,Noyori, Ryoji

, p. 2521 - 2522 (2007/10/03)

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