174831-46-0Relevant academic research and scientific papers
A new preparative method for allylic indium(III) reagents by reductive transmetalation of π-allylpalladium(II) with indium(I) salts
Araki, Shuki,Kamei, Toshiya,Hirashita, Tsunehisa,Yamamura, Hatsuo,Kawai, Masao
, p. 847 - 849 (2007/10/03)
(figure presented) A reductive transmetalation of the π-allylpalladium(II) complexes, generated in situ from a catalytic amount of a palladium(0) complex and a variety of allylic substrates, with indium(I) salts proceeded smoothly in various solvents, providing a new route for allylindium(III) reagents.
Indium-mediated reaction of 1,3-dichloro- and 1,3-dibromopropenes with carbonyl compounds. Generation of novel 3,3-diindiopropene
Araki, Shuki,Hirashita, Tsunebisa,Shimizu, Hidetaka,Yamamura, Hatsuo,Kawai, Masao,Butsugan, Yasuo
, p. 8417 - 8420 (2007/10/03)
Indium-mediated reaction of 1,3-dichloropropene with aldehyde gave syn-chlorohydrin predominantly. A similar reaction of 1,3-dibromopropene gave vinyloxirane and homoallyl alcohol; the former is formed from γ-bromoallylindium via the corresponding bromohydrin, and the latter is considered to be derived from a unique allylic diindium reagent, 3,3-diindiopropene.
A gem-allyl dianion synthon in water
Chen, Dong-Li,Li, Chao-Jun
, p. 295 - 298 (2007/10/02)
The reaction of 1,3-dibromopropene with carbonyl compounds mediated by indium in water gave bis-allylation products connected to the same carbon. Such a reactivity effectively constitutes a gem-allyl dianion synthon.
