17486-95-2Relevant academic research and scientific papers
Asymmetric electrophilic fluorocyclization with carbon nucleophiles
Wolstenhulme, Jamie R.,Rosenqvist, Jessica,Lozano, Oscar,Ilupeju, John,Wurz, Nathalie,Engle, Keary M.,Pidgeon, George W.,Moore, Peter R.,Sandford, Graham,Gouverneur, Veronique
supporting information, p. 9796 - 9800 (2013/09/23)
Twist of 'F'ate: Various helical-shaped fluorinated tetracyclic molecules were prepared by fluorocarbocyclization of prochiral alkenes. The development of a new class of chiral Selectfluor (1) proved instrumental in developing an asymmetric variant of this transformation. These novel chiral N-F reagents are readily accessible by fluorine transfer from shelf-stable N-fluoropyridinium salts. Copyright
