174876-44-9Relevant academic research and scientific papers
Sterically Hindered 1,4-Methylenebenzoquinones in the Synthesis of Six-Membered N-, O-, S-, and Se-Heterocycles
Komissarov, V. N.,Ukhin, L. Yu.,Vetoshkina, L. V.,Dupin, A. M.,Erin, A. N.
, p. 700 - 706 (2007/10/03)
In the presence of acids or bases or on heating 2,6-di-tert-butyl-4-(4,5-dimethoxy-2-phenacylbenzylidene)-2,5-cyclohexadien-1-ones are converted into isochromenes; treatment with hydroxylamine yields isoquinoline derivatives possessing high antioxidant activity.Reactions of these methylenebenzoquinones with elemental sulfur and selenium result in formation of 1,2-dihydro-2-thia(selena)naphthalene 2-oxides.
